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本文报导芳香族羟肟铜(Ⅱ)络合物的电子自旋共振(ESR)谱的研究。讨论了这类配位体上取代基的电子效应对络合物中铜(Ⅱ)的超精细分裂常数A_(Cu)值的影响,以及A_(Cu)值与这些配位体萃取铜的分配系数的关系。
In this paper, the electron spin resonance (ESR) spectra of aromatic hydroxyoxime copper (Ⅱ) complexes were reported. The effects of the electronic effects of the substituents on the ligands on the Cu (Ⅱ) hyperfine splitting constants Cu (Ⅱ) in the complex were discussed, as well as the effect of the A_ (Cu) value and the distribution of copper on these ligands The relationship between the coefficients.