由于含多个亚苯基作为刚棒、低聚醚作为柔性链的刚-柔分子具有很强的微相分离和π-π堆积作用,可以在本体和溶液中产生有效的自组装。分子自组装需要两个条件:驱动力(非共价键的弱相互作用力)和导向作用(分子在空间的互补性)。刚性嵌段的形状不仅决定了分子排列方向、空间尺寸,而且还影响着驱动力的大小。本文综述了以亚苯基为V型刚棒、齐聚醚作为柔性链的刚-柔分子自组装行为,并展望了V型刚-柔分子未来的研究方向。 Due to the strong microphase separation and π-π stacking effect of oligoethers as flexible chains due to the inclusion of multiple phenylene groups as rigid rods, efficient self-assembly in the bulk and solution results. Molecular self-assembly requires two conditions: the driving force (non-covalent bond weak interaction) and the guiding role (molecular in space complementarity). The shape of the rigid block not only determines the molecular orientation, spatial size, but also affects the size of the driving force. In this paper, the rigid-flexible self-assembly behavior of rigid-flexible molecules with phenylethylene as V-shaped rigid rod and polyether as flexible chain is summarized. The future research direction of V-rigid-flexible molecules is also discussed.