综述了烯烃氢甲酰化反应中所应用的膦和亚磷酸酯两大类配体,其研究经历了单磷、双磷及单磷配体再度兴起的过程。列举了一些有代表性的配体及理论。配体研究的发展过程始终围绕着既能提高催化活性又能提高目的产物区域选择性这个主题。 Two classes of phosphine and phosphite ligands used in the hydroformylation of olefins are reviewed. The study has undergone the re-emergence of monophosphorus, diphosphorus and monophosphorus ligands. A few representative ligands and theories are listed. The development of ligand research has always centered around the theme of improving both the catalytic activity and the regioselectivity of the target product.