Divalent metal fluorides MF2 (M=Sr, Mg, Ca) in oxyfluoride tellurite glasses TeO2-BaF2-LaFa were synthesized. The densities, refractive indices and characteristic temperatures of synthesized glasses were measured.The influence of divalent metal fluorides MF2 (M=Sr, Mg, Ca) on the thermal stability of oxyfluoride tellurite glasses TeO2-BaF2-LaF3 were studied. Results show that the replacement of BaF2 by SrF2 and MgF2 can enhance the thermal stability against crystallization of the glass. A glass system with good thermal stability was produced, which could be a potential candidate for the host materials of the fiber devices.