【摘 要】
：
The title compound [Ag(CH3CONHC(S)NH2)2](NO3) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction. It crystallizes
【机 构】
：
New Materials & Function Coordination Chemistry Labboratory,Materials Chemistry Laboratory
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The title compound [Ag(CH3CONHC(S)NH2)2](NO3) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction. It crystallizes in mo-noclinic, space group P21/c with Mr = 406.20 (C6H12Ag N5O5S2), a = 12.0680(6), b = 6.8056(5), c = 18.0173(1)(A。), β = 111.383(4)°, V = 1377.9(2)(A。)3, Z = 4, Dc = 1.958 g/cm3 , F(000) = 808, μ = 1.789 mm-1, R = 0.0361 and wR = 0.1015. Of 4185 reflections ((2θ)max = 55.00°), 3147 were unique (Rint = 0.0174) and 2820 with I > 2σ(I) were used to solve the structure. The silver(I) atom adopts V-shape geometry with the Ag-S bond distance of 2.4271(7) and 2.7229(9)(A。), respectively. Seven atoms of one acetylthiocarbamide ligand are coplanar, while only four atoms of another acetylthio-carbamide ligand are fairly planar. The [Ag(CH3CONHC(S)NH2)2]+ cation and nitrate anion NO3- are connected by hydrogen bonds to form a three dimensional hydrogen bonding network..
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