PARTIAL MELTING AND RECRYSTALLIZATION OF ISOTACTIC POLYPROPYLENE

来源 :高分子科学(英文版) | 被引量 : 0次 | 上传用户:cherrydarling
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A relatively high predetermined crystallization temperature(135℃)was chosen to grow well developed iPP spherulites,then the partial melting was carried out at a temperature of 165℃,where the preformed spherulites were seen to only decrease their size but not completely melted.The crystallization behavior of partially melted isotactic polypropylene (iPP)has been carefully examined by different scanning calorimetry(DSC)and polarized light microscopy(PLM).The experimental results show that at a special annealing temperature(165℃)the melting behavior of iPP includes two parts with different mechanism,one part is the melting of iPP spherulite outside,another is the partial lamellae perfection during longer annealing time in the unmelted spherulite.The conformational orders of the iPP melt decrease with the increase of the annealing temperature.
其他文献
水量调控是解决流域水资源时空分布不均、防止河道断流的有效途径之一。在分析水量调控系统的基础上,建立了年、月、旬自适应水量调度模型框架。采用自适应控制理论和“总量
在新课标下,遗传学实验题是高考常考且较难的试题,学生遇到这类试题就感觉无从下手,但在解这类试题时也是有方法的,如:“正反交方法”在遗传学解题中就常常应用。那么什么是正反交
介绍了一种新型容性设备介质损耗在线监测系统.通过利用现场可编程门阵列(FPGA)同时实现测频、测相位差和自校正等功能,可有效消除零点漂移、电网频率波动和通道传输不一致等
根据脉冲工作状态下半导体激光器激射光谱随结温升高而发生红移的原理,提出了一种测试半导体激光器热弛豫时间的新方法--利用调节取样积分器(Boxcar)取样门,测量光信号脉冲内
通常意义下的功角稳定性和电压稳定性事实上只反映电力系统稳定性的不同方面,作为一个整体,电力系统稳定性本质上是一个综合问题.文中采用向量场正规形理论,对系统稳定运行点
The promotion effect of CO in methane dehydroaromatization was investigated using ~(13)CO probe molecules.By alternative injection of ~(13)CO to the methane fee
1 IntroductionAreca catechu L.(Palmae),commonly known as an important economical seed crop,is widely cultivated in tropical and subtropical areas,including Indi
A model is presented for the simulation of reactive gas-solids flows in large industrial reactors. Circulating fluidized bed (CFB) combustors with several thous
Self-positioning of a shearer is the key technology for mining with a man-less working face. In an underground coal mine all radio navigation; satellite positio
Using GIS, GPS and GPRS, a dynamic management system of ore blending in an open pit mine has been designed and developed. A linear program was established in a