【摘 要】
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CexZr1-xO2 complex oxides doped by transition metal(Fe, Mn, Cu) were prepared by precipitation method. Thermal stability of samples was characterized by XRD, su
【机 构】
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Institute of Nuclear and New Energy Technology,College of Chemical Engineering,Kunming Sino-Platinum
论文部分内容阅读
CexZr1-xO2 complex oxides doped by transition metal(Fe, Mn, Cu) were prepared by precipitation method. Thermal stability of samples was characterized by XRD, surface areas were measured by BET method and reductive property was characterized by TPR. The results show that MnO2 can be dispersed in solid solution after calcined at 1273 K, when the loading is 12%, while Fe and Cu is easy to separate from samples at this temperature. Samples doped simultaneously by Fe, Mn or Fe, Cu demonstrated high reactive property at low temperature. The starting reduction temperature are 413 and 373 K, respectively. TPR results also show a broad range of reductive temperature exists in these bi-metal doped samples.
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