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本文用~(13)C NMR研究甲醛溶液中二羟甲基硝胺(O_2N-N_(CH_2OH)~(CH_2OH)分解动力学,结果表明:分解为一级反应。求出了速率常数,导出了二羟甲基硝胺分解的可能历程。
In this paper, the decomposition kinetics of dimethylolnitrosamine (O_2N-N_ (CH_2OH) ~ (CH_2OH)) in formalin was studied by ~ (13) C NMR. The results showed that the decomposition rate was first order and the rate constant was obtained. Possible process of dimethylol nitramine decomposition.