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对Li-(Mg、Zn、Ni)钒酸盐系统在500—800℃的相图研究发现:(Mg、Zn、Ni)V_2O_6和(Mg、Zn、Ni)_2V_2O_7,二个系统中都有两个主要固溶体,一个以NiV_2O_6(或Ni_2V_2O_7)为主结构,另一个在MgV_2O_6-ZnV_2O_6间形成完全连续型,Mg_2V_2O_7-Zn_2V_2O_7间为MgZnV_2O_7结构型。(Mg、Zn、Ni)_3V_2O_8系统中,整个就是一个固溶体,而Li(Mg、Zn、Ni)VO_4系统中,端员组分相互间也形成不同的固溶体。
The phase diagram of Li- (Mg, Zn, Ni) vanadate system at 500-800 ℃ found that (Mg, Zn, Ni) V_2O_6 and (Mg, Zn, Ni) _2V_2O_7 have two One of the main solid solutions, one dominated by NiV_2O_6 (or Ni_2V_2O_7), and the other formed a completely continuous type between MgV_2O_6-ZnV_2O_6, was MgZnV_2O_7 between Mg_2V_2O_7-Zn_2V_2O_7. (Mg, Zn, Ni) _3V_2O_8 system, the whole is a solid solution, and the Li (Mg, Zn, Ni) VO_4 system, the terminal members also form different solid solutions with each other.