本文制取两类二氮六圜衍生物,1-甲基-二氮六圜-4-二硫代申酸烃酯柠檬酸盐及1-甲基-4-芳基氨基硫代甲醯二氮六圜柠檬酸盐。1-甲基-二氮六圜-4-二硫代甲酸烃酯可由1-甲基-二氮六圜与二硫化碳及乙醇钠作用成1-甲基-二氮六圜-4-二硫代甲酸钠,而后分别与相当的鹵化烃作用制成。1-甲基-4-芳基氨基硫代甲醯二氮六圜可由1-甲基-二氮六圜及相当的异硫氰酸芳基酯在乙醚中作用制成。 In this paper, two types of diazepam derivatives, 1-methyl-diazanthos-4-dithioic acid ester citrate and 1-methyl-4-arylaminothiocarbamate Nitroxonium citrate. The 1-methyl-diazansiose-4-dithiocarbamic acid ester can be formed from 1-methyl-diazanaphthalene with carbon disulfide and sodium ethoxide to give 1-methyl-diazepan-4-dithio Sodium formate, and then with the corresponding role of halogenated hydrocarbons made. 1-Methyl-4-arylaminothiocarbodiazepine can be prepared from the reaction of 1-methyl-diazanilide and the corresponding aryl isothiocyanate in ether.