1、前言目前,合成具有金属性质的高分子材料——高分子金属非常引人注目。这里所谓的金属主要是指电学上的金属性质,即是电的良导体。以往人们通常把铜、铝等金属用作为导电体;把高分子材料用作为绝缘体,提到高分子材料就使人联想起这是绝缘体。从以下二个理由可以说明,高分子金属的出现开辟了高分子应用的新领域。第一,Little预言,高分子金属有可能成为新机理的高温超导体——以excitone(或以极化)为媒介,电子间引力形成电子对(库珀对)。BCS 1, Introduction At present, the synthesis of polymer materials with a metallic nature - polymer metal is very compelling. The so-called metal here mainly refers to the electrical properties of the metal, that is, a good conductor of electricity. In the past, people usually used copper, aluminum and other metals as electrical conductors. When using polymeric materials as insulators, the reference to polymer materials is reminiscent of insulators. From the following two reasons to illustrate the emergence of polymer metals opened up new areas of polymer applications. First, Little predicts that high-molecular metals may become the new mechanism for high-temperature superconductors - induced by excitone (or polarization), where electrons create gravitational pairs (Cooper pairs). BCS