近年来,聚二乙炔的一维特性引起了人们的注意.为了探索这类给体与有机受体形成的电荷转移复合物,从而获得高电导的聚二乙炔单晶,我们采用X射线衍射法对标题复合物进行了晶体结构测定.本文主要叙述该复合物的分子结构和晶体结构.实验部分一、样品制备将82毫克咔唑二乙炔[1,6-di-(N-Carbazolyl-)2,4-hexadiyne,简称DCH],126毫克三硝基芴酮[2,4,7-trinitrofluorenone,简称TNF]分别溶解在25毫升和15毫升分析纯丙酮中, In recent years, the one-dimensional properties of polydiacetylene have drawn people’s attention.In order to explore the charge-transfer complex formed by such donors and organic receptors to obtain highly conductive polydiacetylene single crystals, we use X-ray diffraction The crystal structure of the title compound has been determined.This article mainly describes the molecular structure and crystal structure of the complex.Experimental Part I. Sample Preparation 82 mg of N-Carbazolyl- , 4-hexadiyne (DCH for short), 126 mg of 2,4,7-trinitrofluorenone (TNF) were dissolved in 25 ml of acetone and 15 ml of acetone,