凝胶作为一种半固态的软物质材料近年来得到很多关注。高分子和小分子都可以作为凝胶的胶凝剂,但是由于在形成过程中两者形成的结构交联与否对形成的凝胶影响很大,表现出了明显的不同。而小分子高分子混合凝胶能整合两者的优势,使混合凝胶兼具小分子凝胶的刺激响应性和高分子凝胶的力学性能。本文从高分子凝胶与小分子凝胶的差异化和互补性方面入手,总结了小分子和高分子的混合凝胶的研究进展。 Gels have received much attention as a semi-solid soft material in recent years. Both macromolecules and small molecules can act as gel gelling agents, but the obvious difference is shown because of the great influence on the gel formed by the formation of the crosslinked structure during the formation. The small molecule polymer hybrid gel can combine the advantages of both, so that the hybrid gel combines the stimulus responsiveness of the small molecule gel and the mechanical properties of the polymer gel. In this paper, the differences and complementarities between polymer gels and small-molecule gels are reviewed. The progress of hybrid gels for small molecules and polymers is summarized.