Influence of Voltage on Electric Brush-platingBehavior of a Cauliflower-like Superhydrophobic Ni Coa

来源 :第十一届全国表面工程大会暨第八届全国青年表面工程学术会议 | 被引量 : 0次 | 上传用户:ctk0836
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  Inspired by the microstructures of typical plants leaves surface, such as lotus leaves, red rose petals, etc. a series of cauliflower-like Ni coatings with excellent superhydrophobicity were prepared by an improved electric brush-plating technique. The effect of the plating voltage on thesurface roughness, morphology , chemical composition and wettability of the Ni coatings was investigated by means of Laser scanning confocal microscopy (LSCM), scanning electronic microscope (SEM), X-ray diffraction (XRD), energy-dispersive spectroscopy (EDS), and water contact angle measurements.The results indicate that the evolution of surface morphology on Ni coatings prepared by brush-plating depends strongly on the variation of plating voltage. The microstructure characterization shows that the typical hierarchical cauliflower-like structures formed uniformly on the as-prepared Ni coatings. The combination of the porous morphology and hierarchical cauliflower-like structures plays a crucial role in improving the superhydrophobic property. In absence of surface chemical modification, the Ni coatings exhibit an excellent superhydrophobicity, a high contact angle of 146°. Based on the Cassie-Baxier models, the relationship of two dimensionless geometrical parameters (the aspect ratio and the spacing factor of cauliflower-like structures) and the wetting property of the Ni coatings were investigated. It was demonstrated that to obtain the stable Cassie superhydrophobic state, the aspect ratio and the water contact angle on the basal surface should be as large as possible and the spacing factor should be limited within a specific range for given aspect ratio and water contact angle on the basal surface.
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