Recent Advance in Preparation and Properties of Nitride layer on metal Uranium Surface

来源 :第十一届全国表面工程大会暨第八届全国青年表面工程学术会议 | 被引量 : 0次 | 上传用户:xy59573928
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  Uranium as an important energy material plays a significant role in the national econ my and national defense. However, uranium metal is very active, and it is very easy to be oxidized and corroded in the environment. The corrosion not only leads to the nuclear pollution of environment, but also leads to the deterioration or failure of its components performance. Therefore, it is very important to study the corrosion and oxidation behavior of uranium metal and to find the appropriate an-ti-corrosion treatment technology, which has important scientific research value and great engineering significance. This report will briefly introduce the recent research progress on the corrosion behavior of uranium metal and the preparation and properties of nitride layer on uranium metal surface.It is an important foundation for the design of effective anti-corrosion technology to understand how the metal is oxidized in the environment. In view of the nitriding technology in Ti and Fe-based alloys, the successful application to improve the surface wear resistance and corrosion resistance, the research group has explored ion implantation, laser surface nitriding and glow plasma nitriding tech-nology to prepare various uranium nitrides on uranium surface. The relationship between the prepara-tion technology and the composition as well as structure of the surface layer was studied. By using tran mission electron microscopy (TEM), Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS), it is found that surface nitriding can effectively improve the corrosion resistance of the metal uranium, and the nitride with high nitrogen content exhibits better oxidation resistance than the one with low nitrogen content. In addition, the first principle calculation reveals that the anti-oxidant corrosion mechanism is mainly due to the uranium nitride has changed the adsorption and dissociation behavior of O2 on its surface. The transport of dissociated ions to nitride lattice is hindered, so as to the nitride / metal interface caused by continuous oxidation is prevented. Another interesting finding is that although the nitride thermodyn mically is easily oxidized, but once oxygen ions enter in the lattice of the nitride with high nitrogen content, a more stable structure than nitride can be formed (Oxynitride or Oxygen contained nitride). It can prevent the occurrence of further oxidation corrosion. These findings will contribute to the development of metal uranium surface corrosion protection technology.
其他文献
转炉钢尾渣在海洋领域得到了越来越多的利用,对于其是否会给海洋环境造成危害并没有明确的鉴定结论。本试验对某钢厂转炉钢尾渣进行多点采样,根据相应国家标准对其浸出毒性和腐蚀性进行了全面的分析,经检测转炉钢尾渣不具有危险废物浸出毒性及腐蚀性。
近年来,我国大气环境形势严峻,钢铁企业污染物排放治理一直是我国关注的焦点。为处理竖炉球团生产过程中,产生大量粉尘、SO2 等有害物质,减少对环境造成污染,某钢铁厂决定对现有竖炉增设一套半干法烟气脱硫设施。半干法脱硫工艺具有脱硫效率高、系统简单,运行阻力低,操作维护方便等特点。
近年来,随着污水处理技术的不断成熟,钢铁行业污水处理技术也不断发展,国内钢铁行业越来越多的采用双膜法处理工艺将钢铁污水进行深度处理后回用于生产系统,经过处理后的废水可用于循环水系统以及一些工艺用水。
包钢焦化厂6m 焦炉除尘系统采用地面除尘站袋式除尘系统,该系统从投入运行后改善了焦炉的操作环境,但也暴露出一些问题,随着近年来环保形势日益严峻,以及2015 年1 月1 日新修订的史上最严《环保法》开始实施,现有的除尘效果已经不能满足环保要求,必须通过一系列的改进措施来优化除尘设备的运行效果,并达到国家环境标准要求。
布袋作为袋式除尘器的关键部件,对除尘器的使用效果起决定性作用。本文结合包钢干熄焦环境除尘器生产实际,列举了布袋的常用破损形式,并对布袋破损原因进行了分析,同时总结出不停产在线更换破损布袋的检修方法,对干熄焦环境除尘器稳定、高效运行具有一定的参考价值。
本文对比研究了电弧炉炼钢中两类不同装料方案:一类是100%废钢作原料,此类方案中采用了残余铜含量和价格均不同的两种废钢;另一类方案是使用基于铁矿的经还原加工过的含铁原料(本文中被称作纯净铁材料),如高炉铁水、生铁、直接还原铁和热压铁块,对废钢进行部分替换。
运焦系统除尘烟囱冒烟,环保不达标,通过除尘器风道加装挡板,喷吹管找正,吸尘点加装手动插板阀等措施。减少粉尘外溢,符合大气污染物的排放标准,节约布袋使用,减少使用成本。
针对冶金污水成分复杂,对环境危害性大,需要投入大量的人力物力进行污水处理和冶金废气余热资源因没有合适的用户而被大量浪费的生产现状,本文提出了采用减压蒸馏法处理钢铁工业生产过程污水的污水预处理工艺,即利用钢铁企业低温废气所携带的显热在负压条件下对生产过程污水进行蒸馏,将低温废气温度降低到150℃左右,工艺所产蒸馏水回用于工序新水补水,浓缩后的污水排入污水处理中心进行后续处理,极大地解决了上述生产中实
根据减压蒸馏原理和钢铁企业废水余热共生特点,提出了利用钢铁企业低温废气余热对企业废水进行减压蒸馏的新方法。针对某钢铁企业连铸工序综合废水进行了减压蒸馏实验,并对实验数据进行了分析。实验结果证明,该方法处理后的废水可以满足钢铁企业回用水质要求。
本文介绍了焦炉烟道气脱硫消纳利用焦炉煤气脱硫废液和剩余氨水混合液的原理和实际应用效果,为低成本无害化资源化处置和利用含多种污染成分焦化废水提供了新的解决方案,也为利用闲置的原焦化废水处理系统处理和利用城市生活废水等其它废水创造了条件。
会议