Tuning the net topology of ternary Ag(Ⅰ)-1,2,4,5-tetra(4-pyridyl) benzene-carboxylate Framework:Stru

来源 :中国化学会第十届全国无机化学学术会议 | 被引量 : 0次 | 上传用户:blackboy1221
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  The dye molecule 1,2,4,5-tetra(4-pyridyl)benzene(bztpy),a tetradentate ligand,can be an excellent candidate to construct coordination polymers with photoluminescent properties.1 Here,three novel complexes that based on Ag+and bztpy,named [Ag2(bza)2(μ4-bztpy)](1),[Ag2(μ-ipa)(μ4-bztpy)]·EtOH·3H2O(2)and [Ag3(pda)(μ-pda)1/2(μ4-bztpy)2]·3EtOH·6H2O(3)(Hbza=benzoic acid,H2ipa=isophthalic acid and H2pda = 2,4-pyridinedicarboxylic acid),has been synthesized by the assistant of the auxiliary carboxylates.
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