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A symmetrical sugar-based perylenediimide derivative PTCDI-BAG was synthesized and its aggregate morphologies and formation mechanisms was studied in detail in the mixed solvent system water/ N,N-dimethylformamide (H2O/DMF) with changing volume ratios, by previous research work in our group.However, when the mixed solvent system is changed into ethanol/DMSO, the aggregate morphologies are similar, but their chiralities arc opposite according to recorded circular dichroism (CD) spectra.